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Topic notes

Investigations

Prescribed investigations


Other investigations

Analysis

Resources

Worksheets


Calculating enthalpy changes


Hess Law


Below are the answers to all/most questions on the three exercise sheets above

Bond enthalpies


Standard enthalpy of formation and combustion


Born Haber cycles

Tutorials

flow of heat: this one also helps understanding bonding
Like this one because it also links it to bonding and kinetic theory: heating curves
Some animations on calorimeters: calorimeter1 calorimeter2
Calorimetry experimentsCalorimetry experiment simulations
Hess's law calculations
Tutorial Hess's law
BBC test bite on Hess's law
bond enthalpies
Entropy Gibbs free energy from a biology perspective: Gibbs free energy in biology
Extension: an animation showing enthalpy changes when an ionic substance dissolves: dissolution of ammonium nitrate
BBC bitesize enthalpy of solution

Data sheet

Organic compounds thermodynamic data

Revision

Remember:
  • Check the unit of an enthalpy change; either it is in kJ or kJ mol-1.
  • When calculating molar enthalpy change do not use the mass of the water/surroundings to calculate the number of moles. Also make sure you clearly state the sign i.e + or -.
  • When calculating free energy you should have enthalpy and entropy in the same units either both in kJ or both in J; temperature should be in K.
  • Make sure the state symbols are (g) in your equations defining ionization energy, electron affinity and bond enthalpy.
  • Bond enthalpy is for 1 mole of covalent bonds in gaseous molecules to form gaseous atoms.
  • Bond enthalpy is also an AVERAGE
  • Calculating enthalpy change using bond enthalpies is reactants - products as is using enthalpies of combustion; other are products - reactants.